Carbonatites are perhaps the most unusual of all lava types. Carbonatites are intrusive or extrusive igneous rocks defined by mineralogical composition consisting of greater than 50 percent carbonate minerals. There are only 330 known Carbonatite locations on Earth, most of which are shallow intrusive bodies of calcite-rich igneous rock in the form of volcanic necks, dikes, and cone sheets. It can be seen in places such as the Rhine valley and the East African rift system.
Most carbonatite lava's have low eruption temperatures between 500 and 600 degrees. Although they often resemble flowing lobes of black mud, they are hot enough to display glowing, deep-red colors when seen at night. It has known to have erupted in the active Ol Doinyo Lengai volcano in Tanzania.
Here is a video clip of othe Ol Doniyo Lengai volcano erupting with carbonatite lava.